Quick answer

Exfoliating ingredient derived from unripe fruit; Has properties of both an alpha hydroxy acid and beta hydroxy acid; Ideal exfoliating range is between pH 3-4; Also used as a food additive Key benefits: Evens Skin Tone, Smooths Bumpy Skin.

Malic Acid

AHA

Updated

Butenedioic acid, hydroxy-, (2S)-

Purpose

This fruit-derived ingredient can serve different purposes in cosmetics, including as an exfoliant (when formulated between pH 3-4) and as a pH adjuster.

Rating

BEST

Category

Exfoliant, pH Adjuster/Stabilizer

INCI Purpose

BUFFERING

Benefits

Evens Skin Tone — Brightens and balances complexion for a more uniform appearance
Smooths Bumpy Skin — Refines texture by gently exfoliating rough, uneven patches

Alternative Names

At a Glance

Exfoliating ingredient derived from unripe fruit

Has properties of both an alpha hydroxy acid and beta hydroxy acid

Ideal exfoliating range is between pH 3-4

Also used as a food additive

Article

Malic acid is an exfoliating ingredient derived from unripe fruit. It also occurs naturally in the human body as a by-product from turning carbohydrates into energy. Although it’s technically a beta hydroxy acid ingredient, it is primarily classified as an alpha hydroxy acid (AHA) because its hydroxyl group in the alpha position is believed to be dominant to the beta hydroxyl group. Also, it is not known to be oil-soluble like traditional beta hydroxy acid salicylic acid.

Malic acid is used in cosmetics to adjust a product’s pH and, in an acidic pH range ideally between 3 and 4, as a mild exfoliant that can be used in lower concentrations (typically between 1–2%) to boost the efficacy of other AHA exfoliants such as glycolic and lactic acids.

In foods, malic acid is sometimes added to impart a sour or tart flavor. In its raw form, malic acid appears as white or colorless crystals. It is considered safe as used in leave-on and rinse-off cosmetics.

See: AHA

References

The Journal of Clinical and Aesthetic Dermatology, August 2018, pages 21-28 Molecules, April 2018, page 863 https://wwwcir-safetyorg/sites/default/files/malic%20acidpdf Plastic and Reconstructive Surgery Global Open, December 2016, ePublication Biological Research, January 2015, ePublication Clinical, Cosmetic, and Investigative Dermatology, November 2010, pages 135-142